Product ID:84-0467, HEXANEDIAMINE SOLUTION (SEE SUPPL)
MSDS Date:09/05/2000
FSC:NIIN:Submitter:D DG
Status Code:A
Kit Part:Y
MSDS Number: CLFBC

CAROLINA BIOLOGICAL SUPPLY CO

2700 YORK RD
BURLINGTON, NC 27215-3387
US

Emergency Phone: 800-424-9300

Info Phone: 800-227-1150/910-584-0381

Cage: 59896

CAROLINA BIOLOGICAL SUPPLY CO

BURLINGTON, NC 27215-3387 US

Telephone: 800-227-1150/910-584-0381

Cage: 59896

1,6-HEXANEDIAMINE

CAS: 124-09-4

RTECS: MO1180000

ACGIH TLV: 2.3 MG/M3;0.5 PPM

SODIUM HYDROXIDE

CAS: 1310-73-2

RTECS: WB4900000

OSHA PEL 2 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:ORL-RAT LD50: 750 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:CAUSES BURNS. HARMFUL IF INHALED,
SWALLOWED OR ABSORBED THROUGH SKIN. MAY CAUSE DAMAGE TO KIDNEYS,
LIVER, AND BLOOD. EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE
IRRITATION. INGESTION: MAY CAUSE EXTENS IVE INTERNAL IRRITATION.
INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY TRACT. CHRONIC:
TESTS ON LABORATORY ANIMALS INDICATE HEXANEDIAMINE MAY PRODUCE
ADVERSE REPRODUCTIVE EFFECTS. MUTATION DATA IS C ITED FOR SODIUM
HYDROXIDE.
Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER
Effects of Overexposure:CAUSES BURNS. HARMFUL IF INHALED, SWALLOWED OR
ABSORBED THROUGH SKIN. MAY CAUSE DAMAGE TO KIDNEYS, LIVER, AND
BLOOD. EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION.
INGESTION: MAY CAUSE EXTENS IVE INTERNAL IRRITATION. INHALATION:
MAY CAUSE IRRITATION TO RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:CORROSIVE TO EYES, SKIN & MUCOUS
MEMBRANES. HAMFUL IF INHALED, SWALLOWED OR ABSORBED THROUGH SKIN.
MAY CAUSE DAMAGE TO KIDNEYS, LIVER & BLOOD.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, RAISING AND
LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS. SKIN: THOROUGHLY WASH EXPOSED AREA FOR AT LEAST 15
MINUTES. REM OVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS.

Flash Point:=85.C, 185.F
Lower Limits:0.9
Upper Limits:4.1
Extinguishing Media:USE DRY CHEMICAL, CO2 OR APPROPRIATE FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:THIS SOLUTION IS NOT FLAMMABLE. FUMES OF
HEXANEDIAMINE PRODUCED UPON HEATING MAY, IN FIRE CONDITIONS, BE
FLAMMABLE. FIRE OR EXCESSIVE HEAT MAY PRODUCE AMMONIA, HYDROGEN
CYANIDE, AND CARBON DIOXIDE GAS ES.

Spill Release Procedures:NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO
SEWER WITH GENEROUS AMOUNTS OF WATER.
Neutralizing Agent:NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO SEWER
WITH GENEROUS AMOUNTS OF WATER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED & PROTECTED
AGAINST PHYSICAL DAMAGE. STORE IN A COOL, DRY AREA AWAY FROM ACIDS
AND ACID FUMES.
Other Precautions:WASH GLOVES BEFORE REMOVING. DO NOT BREATHE DUST. DO
NOT GET IN EYES, ON SKIN, OR CLOTHING. RETAINED RESIDUE MAY MAKE
EMPTY CONTAINERS HAZARDOUS; USE CAUTION.

Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE WITH
ADEQUATE VENTILATION.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): YES
Protective Gloves:RUBBER, NEOPRENE, PVC, OR EQUIVALENT.
Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT
ALL TIMES.
Other Protective Equipment:LAB COAT, EYE WASH, AND SAFETY SHOWER.
Work Hygienic Practices:WASH GLOVES BEFORE REMOVING.
Supplemental Safety and Health
CONTINUED FROM PRODUCT ID: THIS IS A KIT CONTAINING : 84-0467,
HEXANEDIAMINE SOLUTION AND 84-0467, SEBACOYL CHLORIDE SOLUTION
(SERIAL#: CLFBG). HCC BASED ON FLASH POINT/BOILING POINT FOR OTHER
PART OF KIT (BP=95F) AND DLAI 4145.11, TABLE B-3.

HCC:F1
Boiling Pt:=204.C, 399.2F
B.P. Text:HEXANEDIAMINE
Melt/Freeze Pt:=41.C, 105.8F
M.P/F.P Text:HEXANEDIAMINE
Vapor Pres:3 MMHG@60 C(HEXANEDIAMINE
Vapor Density:3.8(HEXANE
Spec Gravity:~ 1 @ 20 C
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID WIITH AMMONIA-LIKE ODOR.
Percent Volatiles by Volume:92%

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, ALDEHYDES, KETONES, ANHYDRIDES, PHENOLS, ISOCYANATES.
Stability Condition to Avoid:HEAT & OPEN FLAMES.
Hazardous Decomposition Products:COX, NITROGEN COMPOUNDS, HCN

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED
WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE.

Toxicological Information:TOXICITY DATA: HEXANDIMINE: ORL-RAT LD50: 750
MG/KG, IHL-MUS LCL0: 750 MG/M3/10M, SKIN-RBT LD50: 1110 MG/KG.
SODIUM HYDROXIDE: ORL-RBT LDLO: 500 MG/KG, IPR-MUS LD50: 40 MG/KG.
CHRONIC: TESTS ON LABORA TORY ANIMALS INDICATE HEXANEDIAMINE MAY
PRODUCE ADVERSE REPRODUCTIVE EFFECTS. MUTATION DATA IS CITED FOR
SODIUM HYDROXIDE. TARGET ORGANS: N/A.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:EPA WASTE NUMBERS: NONE.

Transport Information:DOT PROPER SHIPPING NAME: CORROSIVE LIQUID,
N.O.S. (1,6-HEXANEDIAMINE, SODIUM HYDROXIDE), 8, UN1760.

SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312
REPORTING: ACUTE. SARA TITLE III: 1,6-HEXANEDIAMINE: SARA EHS
SECTION 302 TPQ: NO, SARA SECTION 313 CHEMICALS-NAME LIST: NO, SARA
SECTION 313 CHEMICALS-CHEMICA L CATEGORY: NO, CERCLA SECTION 103
RQ (LBS): NO, RCRA SECTION 261.33: NO; SODIUM HYDROXIDE: SARA EHS
SECTION 302 TPQ: NO, SARA SECTION 313 CHEMICALS-NAME LIST: NO, SARA
SECTION 313 CHEMICALS-CHEMICAL CATEGORY: NO, CERCLA SECTION 103
RQ (LBS): YES, RCRA SECTION 261.33: NO
Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY.
State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER.